Photoinitiation
A photoinitiator is a molecule that creates reactive species (free radicals, cations or anions) when exposed to radiation (UV or visible). Synthetic photoinitiators are key components in photopolymers (for example, photo-curable coatings, adhesives and dental restoratives). Some small molecules in the atmosphere … See more Photoinitators can create reactive species by different pathways including photodissociation and electron transfer. As an example of dissociation, hydrogen peroxide can undergo homolytic cleavage, with the O-O bond … See more AIBN Azobisisobutyronitrile is a white powder often not used as a photoinitiator for vinyl-based polymers … See more Peroxides Since molecular oxygen can abstract H atoms from certain radicals, the HOO· radical is easily … See more • Radical initiator See more • vanLoon, Gary W.; Duffy, Stephen J. (2005). Environmental Chemistry: A Global Perspective. New York, NY: Oxford University Press. ISBN 0-19-927499-1. See more WebApr 10, 2024 · The mechanism of photoinitiation in the two cases is depicted in Scheme 6. In this series of dyes, the most red-shifted absorptions were found for SQ2 and SQ3, exhibiting the most extended π-conjugation (See Figure 32 and Table 12). Absorption maxima peaking at 402 and 410 nm were, respectively, determined for SQ2 and SQ3.
Photoinitiation
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WebPhotoinitiation, Photopolymerization, and Photocuring: Fundamentals and Applications Hardcover by Jean-Pierre Fouassier (Author) See all formats … WebMar 29, 2024 · Developing efficient unimolecular visible light-emitting diode (LED) light photoinitiators (PIs) with photobleaching capability, which are essential for various …
WebApr 2, 2024 · Photoinitiation mechanism for the mono-component systems was established by mean of the CO 2 detection tests, and during the ESR spin-trapping experiments. Conversely, photoinitiating mechanism occurring for two-component systems could be determined on the basis of fluorescence quenching experiments. Notably, photoinitiation … WebFurthermore, photoinitiation of the ACT reaction was achieved for the first time under 470 nm blue light using a novel photochromic photoacid. Finally, using multifunctional monomers, solid-state polymer networks were formed using the ACT reaction producing acetal crosslinks. The presence of S,X-acetal bonds results in an increased glass ...
WebIn this study, a series of coumarin chromophore-based oxime-esters were designed and synthesized as visible light photoinitiators (PIs). Interestingly, upon exposure to irradiation using an LED at 405 nm, the investigated oxime-esters (OXEs) could undergo a direct photocleavage, followed by decarboxylation, WebJan 31, 2024 · Photoredox catalysis has driven a revolution in the field of organic chemistry, but direct mechanistic insights into reactions of genuine synthetic utility remain relatively scarce. Herein we report ultrafast time-resolved spectroscopic observation of a bimolecular organocatalyzed photoredox reactio …
WebThe photoinitiation mechanism of these monoamino-substituted anthraquinone derivatives, when combined with iodonium salt, is first clarified using computational quantum …
WebCurrently, multi-component photoinitiation systems, based on electron transfer, and systems based on hydrogen abstraction, are interesting options. The reaction of electron transfer is based on the interaction of an excited electron donor or acceptor with a second component (electron acceptor or donor respectively) in the ground state, which is ... incorporated with or inWebPhotoinitiation and Photoinhibition for Subdiffraction Photolithography Timothy F. Scott,1* Benjamin A. Kowalski,2 Amy C. Sullivan,2† Christopher N. Bowman,1 Robert R. McLeod2‡ … incorporated within meaningWebPhotoinitiators for white coatings, usually pigmented with TiO 2, require strong absorption in the relatively narrow spectral region of 360–400 nm, below which TiO 2 absorbs strongly … inciweb trail creekWebSummary Photoinitiators. Norish type I initiators are typically compounds containing benzoyl groups which undergo cleavage when exposed to UV light to generate two free radicals of … incorporated with 뜻WebFeb 1, 2009 · The spatio-temporal photoinitiation rate, R i, was calculated from the photoinitiator consumption rate (Eq. (5)) and the results are presented in Fig. 7, Fig. 8. At … incorporated zoneWebSep 13, 2024 · Industrial photoinitiation is a complex business, which is becoming ever more complex owing to new technical and non-technical challenges, but in doing so it presents chemists with a wealth of inciweb todayWebApr 2, 2024 · Photoinitiation mechanism for the mono-component systems was established by mean of the CO 2 detection tests, and during the ESR spin-trapping experiments. … incorporated with or into